Lesson No. 2 · Lesson Explanation · Pages 16–29
Prepared by: Anurag Santosh Maurya
Today we know about 118 elements. Studying all of them separately would be impossible without any order. Scientists spent many years finding the best way to arrange (classify) elements based on their properties. This lesson tells you about that journey — from Dobereiner's simple Triads in 1817, all the way to the Modern Periodic Table with 118 elements today!
• How elements were classified over different time periods
• Dobereiner's Triads, Newlands' Law of Octaves, Mendeleev's Periodic Table
• Modern Periodic Law, structure of Modern Periodic Table
• Periodic trends: Valency, Atomic Size, Metallic/Non-metallic character
From just 30 elements in 1800 to 118 elements today — here is the amazing journey!
Classification of elements means arranging all elements into groups based on their similar properties, so that they are easier to study, compare, and remember.
The first (and simplest) classification was into just two groups. Later, a third was added:
| Type | Properties | Examples |
|---|---|---|
| Metals | Shiny, good conductors of heat & electricity, malleable, ductile, lose electrons | Iron (Fe), Gold (Au), Copper (Cu), Sodium (Na), Potassium (K) |
| Non-metals | Poor conductors, dull, brittle (if solid), gain electrons | Oxygen (O), Carbon (C), Nitrogen (N), Sulfur (S), Chlorine (Cl) |
| Metalloids | Show properties of BOTH metals and non-metals | Silicon (Si), Arsenic (As), Germanium (Ge), Boron (B) |
As more elements were discovered, just three groups were not enough. Scientists needed a system that could show relationships between all elements AND help predict properties of undiscovered ones.
| Nationality: | German |
| Year of Work: | 1817 |
| Basis: | Atomic Mass |
| Contribution: | Grouped elements into sets of three (Triads). Middle element's mass = average of first and third. |
Imagine three brothers. The youngest weighs 7 kg and the oldest weighs 39 kg. Döbereiner noticed that the middle brother's weight would be close to the average: (7 + 39) ÷ 2 = 23 kg. In chemistry, this was exactly what happened with Lithium (7), Sodium (23), and Potassium (39)! Döbereiner found this for several groups of three elements — he called them "Triads".
A Triad is a group of three elements with similar chemical properties, arranged in increasing order of atomic mass. The atomic mass of the middle element is approximately equal to the average (mean) of the atomic masses of the first and third elements.
Formula: Middle element's mass ≈ (First element's mass + Third element's mass) ÷ 2
| Triad | Element 1 (a) | Mean = (a+c)÷2 | Element 2 (actual mass) | Element 3 (c) |
|---|---|---|---|---|
| Li, Na, K | Lithium (Li) = 6.9 | (6.9 + 39.1) ÷ 2 = 23.0 | Sodium (Na) = 23.0 ✓ | Potassium (K) = 39.1 |
| Ca, Sr, Ba | Calcium (Ca) = 40.1 | (40.1 + 137.3) ÷ 2 = 88.7 | Strontium (Sr) = 87.6 ✓ | Barium (Ba) = 137.3 |
| Cl, Br, I | Chlorine (Cl) = 35.5 | (35.5 + 126.9) ÷ 2 = 81.2 | Bromine (Br) = 79.9 ✓ | Iodine (I) = 126.9 |
| Nationality: | English (British) |
| Year of Work: | 1866 |
| Basis: | Atomic Mass (arranged in increasing order) |
| Key Idea: | Every 8th element has properties similar to the 1st element — just like musical octaves! |
Newlands noticed something amazing. In Indian classical music, we have 7 notes: Sa Re Ga Ma Pa Dha Ni. After the 7th note, the 8th note "Sa" comes again — at a higher pitch. This is called a "Saptak".
Newlands found the SAME pattern in elements! When arranged by atomic mass, every 8th element showed properties similar to the 1st element. He named this the Law of Octaves — because an octave in music also has 8 notes.
Example: Lithium (Li) is 1st. Sodium (Na) is the 8th element. Both Li and Na are soft metals that react vigorously with water!
When elements are arranged in increasing order of atomic mass, every 8th element has properties similar to the 1st element. This is called the Law of Octaves.
| Musical Note | Do (Sa) | Re | Mi (Ga) | Fa (Ma) | So (Pa) | La (Dha) | Ti (Ni) |
|---|---|---|---|---|---|---|---|
| Row 1 | H | Li | Be | B | C | N | O |
| Row 2 | F | Na | Mg | Al | Si | P | S |
| Row 3 | Cl | K | Ca | Cr | Ti | Mn | Fe |
| Row 4 | Co & Ni | Cu | Zn | Y | In | As | Se |
| Row 5 | Br | Rb | Sr | Ce & La | Zr | — | — |
Note: Li and Na both come under 'Re' (2nd position). Both have similar properties — the Law of Octaves works here!
| Nationality: | Russian |
| University: | Professor at St. Petersburg University, Russia |
| Year of Work: | 1869–1872 |
| Basis: | Atomic Mass (in increasing order) |
| Greatest Achievement: | Created Periodic Table of 63 elements AND predicted properties of undiscovered elements! |
Mendeleev made a separate card for every known element, writing its atomic mass and properties on it. He then spread all 63 cards on a table and kept arranging them, like solving a huge jigsaw puzzle.
He noticed that elements with similar properties appeared at regular intervals when arranged by atomic mass. When he saw a gap in his arrangement, instead of forcing an element there, he LEFT IT EMPTY — and said: "An element with these properties will be discovered someday."
He was right! Gallium (1875), Scandium (1879), and Germanium (1886) were discovered later — their properties matched his predictions almost perfectly!
"Properties of elements are a periodic function of their atomic masses."
This means: When arranged in increasing order of atomic mass, elements with similar properties appear repeatedly at regular intervals (periodically).
Mendeleev corrected wrong atomic masses so elements fell in the right place. E.g., Beryllium's mass was corrected from 14.09 → 9.4, so it was placed before Boron.
Left gaps for undiscovered elements and predicted their properties. 'Eka-aluminum' (→ Gallium), 'Eka-silicon' (→ Germanium), 'Eka-boron' (→ Scandium) — all predicted accurately!
When noble gases (He, Ne, Ar) were discovered in the late 19th century, Mendeleev created a 'Zero Group' without disturbing the rest of the table.
For the first time, all known elements were arranged in one table, making it easy to study, compare, and predict chemical behaviour.
| Property | Eka-Aluminum (Mendeleev's Prediction, 1871) | Gallium — Ga (Actual, Discovered 1875) |
|---|---|---|
| Atomic Mass | 68 | 69.7 |
| Density (g/cm³) | 5.9 | 5.94 |
| Melting Point | Low | 30.2°C (melts in your hand!) |
| Formula of Chloride | ECl₃ | GaCl₃ |
| Formula of Oxide | E₂O₃ | Ga₂O₃ |
| Nature of Oxide | Amphoteric oxide | Amphoteric oxide |
Cobalt (Co) and Nickel (Ni) have the same whole-number atomic mass (58). So which comes first? This created confusion in Mendeleev's table.
Isotopes (same element, different masses) were discovered later. Since Mendeleev arranged by mass, where should isotopes be placed? This was a major problem.
The increase in atomic mass was not regular, so it was impossible to predict how many elements existed between two heavy elements.
Hydrogen behaves like alkali metals (Group I) in some ways and like halogens (Group VII) in others. Mendeleev could NOT fix its position. This problem is still not fully solved!
| Nationality: | English (British) |
| Year of Work: | 1913 |
| Experiment: | Used X-ray tube experiments on elements. Found that Atomic Number (Z) = number of protons in nucleus = true fundamental property. |
| Key Contribution: | Replaced Atomic Mass with Atomic Number as the basis for classification. |
| Sad Fact: | Moseley was only 27 years old when he died in World War I. He could have won the Nobel Prize. |
"Properties of elements are a periodic function of their atomic numbers."
Atomic Number (Z) = Number of protons in the nucleus of an atom.
This solved the Co-Ni problem! Co has Z=27, Ni has Z=28 → Co comes before Ni. ✓
Isotopes have same Z → placed in the SAME group. ✓
| Point | Mendeleev's Law | Modern Periodic Law |
|---|---|---|
| Basis | Atomic Mass | Atomic Number (Z) |
| Year | 1869 | 1913 |
| Scientist | Mendeleev (Russia) | Moseley (England) |
| Co, Ni Problem | Could NOT resolve | Solved ✓ (Co Z=27 before Ni Z=28) |
| Isotopes | Problem remained | No problem (same Z = same group) ✓ |
The Modern Periodic Table (also called the Long Form of the Periodic Table) arranges all 118 elements in increasing order of atomic number. It has 7 horizontal rows (periods) and 18 vertical columns (groups).
| Feature | Details |
|---|---|
| Periods (Rows) | 7 horizontal rows. Period 1 to Period 7. Going left to right, electrons fill the same shell. |
| Groups (Columns) | 18 vertical columns. Group 1 to Group 18. Same group = same number of valence electrons. |
| Total Elements | 118 elements — all 118 boxes are now filled! |
| Lanthanide & Actinide Series | Shown separately at the bottom (f-block). Lanthanides are Period 6, Actinides are Period 7. |
| s-block | Groups 1 and 2. Alkali metals and Alkaline Earth metals. 1 or 2 valence electrons. |
| p-block | Groups 13–18. Contains metals, non-metals, metalloids, noble gases. Zig-zag line here. |
| d-block | Groups 3–12. Transition elements (Fe, Cu, Zn, Cr, Mn etc.). |
| f-block | Lanthanide & Actinide series. All actinides (Z=90–103) are radioactive. |
Uranium (U) has atomic number 92. All elements beyond uranium — from Z=93 to 118 — are man-made in laboratories. They are all radioactive, unstable, and exist for only a very short time!
All elements in the same group have the same number of valence electrons. This is why they have similar chemical properties!
| Group | Family Name | Valence Electrons | Example Elements & Configuration |
|---|---|---|---|
| Group 1 | Alkali Metals | 1 | Li (2,1) Na (2,8,1) K (2,8,8,1) |
| Group 2 | Alkaline Earth Metals | 2 | Be (2,2) Mg (2,8,2) Ca (2,8,8,2) |
| Group 17 | Halogens | 7 | F (2,7) Cl (2,8,7) Br (2,8,18,7) |
| Group 18 | Noble Gases | 8 (He = 2) | He (2) Ne (2,8) Ar (2,8,8) |
All elements in the same period have the same number of electron shells. A new period starts when a new electron shell begins filling.
| Period | Shells Filled | Elements | Number of Elements |
|---|---|---|---|
| Period 1 | K only | H, He | 2 (K shell capacity = 2) |
| Period 2 | K, L | Li, Be, B, C, N, O, F, Ne | 8 (L shell capacity = 8) |
| Period 3 | K, L, M | Na, Mg, Al, Si, P, S, Cl, Ar | 8 (due to octet rule, not 18) |
| Period 4 | K, L, M, N | K to Kr (includes d-block) | 18 |
| Shell | n | Formula: 2n² | Max Electrons |
|---|---|---|---|
| K | 1 | 2 × 1² = 2 | 2 |
| L | 2 | 2 × 2² = 8 | 8 |
| M | 3 | 2 × 3² = 18 | 18 |
| N | 4 | 2 × 4² = 32 | 32 |
When properties of elements are compared along a period or down a group, they change in a regular (periodic) pattern. These are called Periodic Trends. We study three main trends:
Valency is the combining capacity of an element. It is determined by the number of valence electrons (electrons in the outermost shell).
| Direction | Trend in Valency | Example |
|---|---|---|
| Left → Right in Period | Increases from 1 to 4, then decreases (4 → 0) | Period 3: Na(1), Mg(2), Al(3), Si(4), P(3), S(2), Cl(1), Ar(0) |
| Top → Bottom in Group | Valency remains THE SAME | Group 1: Li(1), Na(1), K(1), Rb(1) — all valency 1 |
Atomic Radius is the distance between the nucleus of an atom and its outermost electron shell. Measured in picometers (pm). (1 pm = 10⁻¹² m)
More protons → stronger pull on electrons → electrons pulled closer → smaller atom.
New electron shell added → electrons farther from nucleus → bigger atom.
Period 2 elements (left → right): Li = 152 pm, Be = 111 pm, B = 88 pm, C = 77 pm, N = 74 pm, O = 66 pm
Li (leftmost) is biggest, O is smallest — proves the trend! ✓
Group 1 elements (top → bottom): Li=152, Na=186, K=231, Rb=244, Cs=262 pm
Goes on increasing as we go down the group. ✓
Electropositivity (Metallic Character): Tendency of an atom to LOSE electrons and form a positive ion (cation). This is metallic character.
Electronegativity (Non-Metallic Character): Tendency of an atom to GAIN electrons and form a negative ion (anion). This is non-metallic character.
| Direction | Metallic Character | Non-Metallic Character | Reason |
|---|---|---|---|
| Left → Right in Period | Decreases ↓ | Increases ↑ | Nuclear charge increases → harder to lose electrons → easier to gain electrons. |
| Top → Bottom in Group | Increases ↑ | Decreases ↓ | New shell added → valence electrons far from nucleus → easier to lose them. |
A zig-zag line in the p-block separates metals from non-metals:
Left of line → Metals | On the line → Metalloids | Right of line → Non-metals
| Element | Symbol | Physical State at Room Temp. | Colour |
|---|---|---|---|
| Fluorine | F₂ | Gas | Pale yellow |
| Chlorine | Cl₂ | Gas | Greenish-yellow |
| Bromine | Br₂ | Liquid | Reddish-brown |
| Iodine | I₂ | Solid | Violet/Dark grey |
As you go down Group 17: Gas → Gas → Liquid → Solid. This is gradation!
| Element | Reaction with Water |
|---|---|
| Beryllium (Be) | Does NOT react with water |
| Magnesium (Mg) | Reacts slowly with STEAM only (not cold water) |
| Calcium (Ca) | Reacts with cold water at room temperature |
| Strontium (Sr) | Reacts faster with cold water |
| Barium (Ba) | Reacts most vigorously with cold water |
Reactivity increases going DOWN the group (Be → Mg → Ca → Sr → Ba). This is gradation!
Lesson No. 2 · Quick Revision · Anurag Santosh Maurya
| Scientist | Year | Country | Basis | Contribution | Main Limitation |
|---|---|---|---|---|---|
| Dobereiner | 1817 | Germany | Atomic Mass | Triads — groups of 3 similar elements. Middle mass ≈ average of 1st & 3rd. | Not all elements fit into triads. |
| Newlands | 1866 | England | Atomic Mass | Law of Octaves — every 8th element similar to 1st. | Works only up to Calcium. 2 elements in 1 box. |
| Mendeleev | 1869–72 | Russia | Atomic Mass | Periodic Table of 63 elements. Predicted undiscovered elements. | H position unclear. Co-Ni problem. Isotope problem. |
| Moseley | 1913 | England | Atomic Number | Modern Periodic Law — Z is the true basis. Solved Co-Ni & isotope problems. | H position still debated. |
| Term | One-Line Definition |
|---|---|
| Element | Pure substance made of only one type of atom. |
| Atomic Mass | Average mass of one atom of an element (in amu). |
| Atomic Number (Z) | Number of protons in the nucleus. (Z = electrons in neutral atom) |
| Triad | Group of 3 elements where middle mass ≈ average of 1st and 3rd. (Dobereiner) |
| Law of Octaves | Every 8th element similar to the 1st when arranged by atomic mass. (Newlands, 1866) |
| Mendeleev's Periodic Law | Properties are periodic function of ATOMIC MASSES. |
| Modern Periodic Law | Properties are periodic function of ATOMIC NUMBERS. |
| Period | Horizontal row. Same period = same number of electron shells. |
| Group | Vertical column. Same group = same valence electrons → similar properties. |
| Valency | Combining capacity; determined by number of valence electrons. |
| Atomic Radius | Distance from nucleus to outermost shell. Measured in picometers (pm). |
| Electropositivity | Tendency to LOSE electrons → metallic character. |
| Electronegativity | Tendency to GAIN electrons → non-metallic character. |
| Isotopes | Same element, same Z, but different atomic mass. Same group in modern table. |
| Noble Gases | Group 18. Full valence shell. Valency = 0. Very unreactive. |
| Transition Elements | d-block elements (Groups 3–12). Variable valency. E.g., Fe, Cu, Zn. |
| Property | → Across Period (Left to Right) | ↓ Down Group (Top to Bottom) |
|---|---|---|
| Atomic Radius | Decreases ↓ | Increases ↑ |
| Valency | 1→2→3→4→3→2→1→0 | Remains SAME |
| Metallic Character | Decreases ↓ | Increases ↑ |
| Non-Metallic Character | Increases ↑ | Decreases ↓ |
| Electropositivity | Decreases ↓ | Increases ↑ |
| Electronegativity | Increases ↑ | Decreases ↓ |
| Number of Shells | Same (stays constant) | Increases (new shell each period) |
| Valence Electrons | Increases by 1 each time | Same (same group = same valence e⁻) |
Formula: Is middle element's mass ≈ (1st mass + 3rd mass) ÷ 2?
| Group | Element 1 (a) | Element 2 (actual) | Element 3 (c) | (a+c)÷2 | Is it a Triad? |
|---|---|---|---|---|---|
| Li, Na, K | Li = 6.9 | Na = 23.0 | K = 39.1 | (6.9+39.1)÷2 = 23.0 | Yes ✓ |
| Ca, Sr, Ba | Ca = 40.1 | Sr = 87.6 | Ba = 137.3 | (40.1+137.3)÷2 = 88.7 | Yes ✓ (≈87.6) |
| Cl, Br, I | Cl = 35.5 | Br = 79.9 | I = 126.9 | (35.5+126.9)÷2 = 81.2 | Yes ✓ (≈79.9) |
| Mg, Ca, Sr | Mg = 24.3 | Ca = 40.1 | Sr = 87.6 | (24.3+87.6)÷2 = 55.95 | No ✗ (55.95 ≠ 40.1) |
| S, Se, Te | S = 32.1 | Se = 79.0 | Te = 127.6 | (32.1+127.6)÷2 = 79.85 | Yes ✓ (≈79.0) |
| Be, Mg, Ca | Be = 9.0 | Mg = 24.3 | Ca = 40.1 | (9.0+40.1)÷2 = 24.55 | Yes ✓ (≈24.3) |
| Element | Z | Interesting Fact |
|---|---|---|
| Gallium (Ga) | 31 | Melts in your palm! Melting point = 30.2°C. Predicted by Mendeleev as 'Eka-Aluminum' (1871). Discovered 1875. |
| Fluorine (F) | 9 | Most electronegative element in the entire periodic table. Most reactive non-metal. Used in toothpaste! |
| Cesium (Cs) | 55 | Largest atomic radius in Group 1 (stable elements). Most electropositive. Melts at just 28.5°C. |
| Uranium (U) | 92 | Heaviest naturally occurring element. All elements Z=93 to 118 are man-made in labs! |
| Helium (He) | 2 | Smallest atom. Noble gas. Valency = 0. Used in balloons (lighter than air and non-flammable). |
| Scandium (Sc) | 21 | Mendeleev predicted it as 'Eka-boron' (mass ≈ 44). Discovered 1879. Properties matched perfectly! |
| Germanium (Ge) | 32 | Predicted as 'Eka-silicon'. Discovered 1886. This was Mendeleev's most accurate prediction. |
1. Corrected atomic masses (e.g., Be: 14.09 → 9.4)
2. Left gaps for undiscovered elements + predicted their properties (Ga, Sc, Ge all matched!)
3. Added Zero Group for noble gases without disturbing the table
1. Co and Ni problem (same atomic mass → sequence unclear)
2. Isotopes problem (different mass, same element → where to place?)
3. Non-uniform rise in mass (can't predict how many elements between two heavy elements)
4. Hydrogen position unclear (similar to Group I AND Group VII)